Colloidal crystal templating of 3DOM materials (inverse opals, inverted opals)
  • Ergang, N. S.; Lytle, J. C.; Yan, H.; Stein, A.; “The Effect of a Macropore Structure on Cycling Rates of LiCoO2” J. Electrochem. Soc. 2005, in press.
  • Lee, K. T.; Lytle, J. C.; Ergang, N. S.; Oh, S. M.; Stein, A.; “Synthesis and Rate Performance of Monolithic Macroporous Carbon Electrodes for Lithium Secondary Batteries”, Adv. Funct. Mater. 2005, 15, 547-556.
  • Zhang, K.; Yan, H.; Stein, A.; Francis, L. F.; "Apatite Converted from 3-D Ordered Macroporous Sol-Gel Bioactive Glass (3DOM-BG) Particles", J. Am. Ceram. Soc. 2005, 88, 587-592.
  • Lytle, J. C.; Yan, H.; Turgeon, R. T.; Stein, A.; “Multistep, Low Temperature Pseudomorphic Transformations of Nanostructured Silica to Titania via a Titanium Oxyfluoride Intermediate”, Chem. Mater. 2004, 16, 3829-3837.
  • Lytle, J. C.; Yan, H.; Ergang, N. S.; Smyrl, W. H.; Stein, A.; “Structural and electrochemical properties of three-dimensionally ordered macroporous tin(IV) oxide films”, J. Mater. Chem. 2004, 14, 1616-1622.
  • Toivola, Y.; Stein, A.; Cook, R. F.; "Depth-Sensing Indentation Response of Ordered Silica Foam", J. Mater. Res. 2004, 19, 260-271.
  • Blanford, C. F.; Carter, C. B.; Stein, A.; “A Method for Determining Void Arrangements in Inverse Opals”, J. Microscopy 2004, 216(3), 263-287.
  • Invited review chapter: Schroden, R. C.; Stein, A.; "3D Ordered Macroporous Materials", Colloids and Colloid Assemblies: Synthesis, Modification, Organization and Utilization of Colloid Particles, F. Caruso (ed.), Wiley-VCH, Weinheim, Germany, 2004, 465-493.
  • Stein, A.; Holland, B. T.; Blanford, C. F.; Yan, H.; "Synthesis of Macroporous Structures"; U. S. Patent 2004, 6,680,013.
  • Al-Daous, M. A.; Stein, A.; "Preparation and Catalytic Evaluation of Macroporous Crystalline Sulfated Zirconium Dioxide Templated with Colloidal Crystals", Chem. Mater. 2003, 15, 2638-2645.
  • Sokolov, S.; Stein, A.; "Preparation and Characterization of Macroporous gamma-LiAlO2", Mater. Letters 2003, 57, 3593-3597.
  • Sokolov, S.; Bell, D.; Stein, A.; "Preparation and Characterization of Macroporous alpha-Alumina", J. Am. Ceram. Soc. 2003, 86, 1481-1486.
  • Yan, H.; Sokolov, S.; Lytle, J. C.; Stein, A.; Zhang, F.; Smyrl, W. H.; "Colloidal-Crystal-Templated Synthesis of Ordered Macroporous Electrode Materials for Lithium Secondary Batteries", J. Electrochem. Soc. 2003, 150, A1102-A1107.
  • Zhang, K.; Yan, H.; Bell, D. C.; Stein, A.; Francis, L. F.; "Effects of Materials Parameters on Mineralization and Degradation of Sol-gel Bioactive Glasses with 3D-ordered Macroporous (3DOM) Structures", J. Biomed. Mater. Res. 2003, 66A, 860-869.
  • Invited review chapter: Stein, A.; Schroden, R. C.; “Designing Porous Solids Over Multiple Pore Size Regimes” in Nanostructured Catalysts, edited by S. L. Scott, C. M. Crudden, C. W. Jones, Kluwer-Plenum series on Nanostructure Science and Technology Vol. 3, 2002, 257-276, Kluwer-Plenum: Dordrecht, Netherlands.
  • Schroden, R. C.; Al-Daous, M.; Sokolov, S.; Melde, B. J.; Lytle, J. C.; Stein, A.; Carbojo, M. C.; Fernández, J. T.; Rodríguez, E. E.; "Hybrid Macroporous Materials for Heavy Metal Ion Adsorption", J. Mater. Chem. 2002, 12, 3261-3267.
  • Melde, B. J.; Stein, A.; "Periodic Macroporous Hydroxyapatite-containing Calcium Phosphates", Chem. Mater. 2002, 14, 3326-3331.
  • Schroden, R. C.; Al-Daous, M.; Blanford, C. F.; Stein, A.; "Optical Properties of Inverse Opal Photonic Crystals", Chem. Mater. 2002, 14, 3305-3315.
  • Yan, H.; Blanford, C. F.; Lytle, J. C.; Carter, C. B.; Smyrl, W. H.; Stein, A.; "Influence of Processing Conditions on Structures of 3D Ordered Macroporous Metals Prepared by Colloidal Crystal Templating", Chem. Mater. 2001, 13, 4314-4321.
  • Invited review: Stein, A.; Schroden, R. C.; "Colloidal Crystal Templating of Three-Dimensionally Ordered Macroporous Solids-Materials for Photonics and Beyond", Current Opinion in Solid State & Materials Science 2001, 5, 553-564.
  • Schroden, R. C.; Al-Daous, M.; Stein, A.; "Self-Modification of Spontaneous Emission by Inverse Opal Silica Photonic Crystals", Chem. Mater. 2001, 13, 2945-2950.
  • Johnson, B. J. S.; Stein, A.; “Surface Modification of Mesoporous, Macroporous, and Amorphous Silica with Catalytically Active Polyoxometalate Clusters”, Inorg. Chem. 2001, 40, 801-808.
  • Yan, H.; Zhang, K.; Blanford, C. F.; Francis, L. F.; Stein, A.; "In Vitro Hydroxycarbonate Apatite Mineralization of CaO-SiO2 Sol-gel Glasses with a Three-Dimensionally Ordered Macroporous Structure", Chem. Mater. 2001, 13, 1374-1382.
  • Schroden, R. C.; Blanford, C. F.; Melde, B. J.; Johnson, B. J. S.; Stein., A.; "Direct Synthesis of Ordered Macroporous Silica Materials Functionalized with Polyoxometalate Clusters", Chem. Mater. 2001, 13, 1074-1081.
  • Invited review: Stein, A.; "Sphere Templating Methods for Periodic Porous Solids", Microporous & Mesoporous Materials 2001, 44-45, 227-239.
  • Invited review: Blanford, C. F.; Yan, H., Schroden, R. C.; Al-Daous, M.; Stein, A.; "Gems of Chemistry and Physics: Three-Dimensionally Ordered Macroporous (3DOM) Metal Oxides", Adv. Mater. 2001, 13, 401-407.
  • Blanford, C. F.; Schroden, R. C.; Al-Daous, M.; Stein, A.; "Tuning Solvent-Dependent Color Changes of Three-Dimensionally Ordered Macroporous (3DOM) Materials Through Compositional and Geometric Modifications", Adv. Mater. 2001, 13, 26-29.
  • Krivorotov, I. N.; Yan, H.; Dahlberg, E. D.; Stein, A.; "Exchange Bias in Macroporous Co/CoO", J. Magn. Magn. Mater. 2001, 226-230, 1800-1802.
  • Yan, H.; Blanford, C. F.; Smyrl, W. H.; Stein, A.; "Preparation and Structure of 3D Ordered Macroporous Alloys by PMMA Colloidal Crystal Templating", Chem. Commun. 2000, 1477-1478.
  • Yan, H.; Blanford, C. F.; Holland, B. T., Smyrl, W. H.; Stein, A.; "General Synthesis of Periodic Macroporous Solids by Templated Salt Precipitation and Chemical Conversion", Chem. Mater. 2000, 12, 1134-1141.
  • Yan, H.; Blanford, C. F.; Holland, B. T.; Parent, M.; Smyrl, W. H.; Stein, A.; "A Chemical Synthesis of Periodic Macroporous NiO and Metallic Ni", Adv. Mater. 1999, 11, 1003-1006.
  • Holland, B. T.; Abrams, L.; Stein, A.; "Dual Templating of Macroporous Silicates with Zeolitic Microporous Frameworks", J. Am. Chem. Soc. 1999, 121, 4308-4309.
  • Blanford, C. F.; Do, T. N.; Holland, B. T.; Stein, A.; "Synthesis of Highly Ordered Macroporous Minerals: Extension of the Synthetic Method to other Metal Oxides and Organic-Inorganic Composites", in Lednor, P. W.; Nagaki, D. A.; Thompson, L. T. (eds.); Mater. Res. Soc. Symp. Proc. 1999, Vol. 549 (Advanced Catalytic Materials), 61-66.
  • Holland, B. T.; Blanford, C. F.; Do, T.; Stein, A.; "Synthesis of Highly Ordered Three-Dimensional Macroporous Structures of Amorphous or Crystalline Inorganic Oxides, Phosphates and Hybrid Composites", Chem. Mater. 1999, 11, 795-805.
  • Holland, B. T.; Blanford, C. F.; Stein, A.; "Synthesis of Highly Ordered Three-Dimensional Mineral Honeycombs with Macropores", Science 1998, 281, 538-540.

Inorganic surface modification of mesoporous sieves

Organic modification of mesoporous sieves

Catalysts and catalyst supports

Photonic crystals

Bioactive glasses and hydroxyapatite

  • Zhang, K.; Yan, H.; Stein, A.; Francis, L. F.; "Apatite Converted from 3-D Ordered Macroporous Sol-Gel Bioactive Glass (3DOM-BG) Particles", J. Am. Ceram. Soc. 2005, 88, 587-592.
  • Zhang, K.; Yan, H.; Bell, D. C.; Stein, A.; Francis, L. F.; "Effects of Materials Parameters on Mineralization and Degradation of Sol-gel Bioactive Glasses with 3D-ordered Macroporous (3DOM) Structures", J. Biomed. Mater. Res. 2003, 66A, 860-869.
  • Melde, B. J.; Stein, A.; "Periodic Macroporous Hydroxyapatite-containing Calcium Phosphates", Chem. Mater. 2002, 14, 3326-3331.
  • Yan, H.; Zhang, K.; Blanford, C. F.; Francis, L. F.; Stein, A.; "In Vitro Hydroxycarbonate Apatite Mineralization of CaO-SiO2 Sol-gel Glasses with a Three-Dimensionally Ordered Macroporous Structure", Chem. Mater. 2001, 13, 1374-1382.

Lithium battery materials

  • Ergang, N. S.; Lytle, J. C.; Yan, H.; Stein, A.; “The Effect of a Macropore Structure on Cycling Rates of LiCoO2” J. Electrochem. Soc. 2005, in press.
  • Lee, K. T.; Lytle, J. C.; Ergang, N. S.; Oh, S. M.; Stein, A.; “Synthesis and Rate Performance of Monolithic Macroporous Carbon Electrodes for Lithium Secondary Batteries”, Adv. Funct. Mater. 2005, 15, 547-556.
  • Lytle, J. C.; Yan, H.; Ergang, N. S.; Smyrl, W. H.; Stein, A.; “Structural and electrochemical properties of three-dimensionally ordered macroporous tin(IV) oxide films”, J. Mater. Chem. 2004, 14, 1616-1622.
  • Yan, H.; Sokolov, S.; Lytle, J. C.; Stein, A.; Zhang, F.; Smyrl, W. H.; "Colloidal-Crystal-Templated Synthesis of Ordered Macroporous Electrode Materials for Lithium Secondary Batteries", J. Electrochem. Soc. 2003, 150, A1102-A1107.
  • Aronson, B. J.; Blanford, C. F.; Stein, A.; "Synthesis, Characterization, and Ion-Exchange Properties of Zinc and Magnesium Manganese Oxides Confined within MCM-41 Channels", J. Phys. Chem. B 2000, 104, 449-459.
  • Aronson, B. J.; Kinser, A. J.; Passerini, S.; Smyrl, W. H.; Stein, A.; "Zinc and magnesium manganese oxides as lithium intercalation hosts", Proc.-Electrochem. Soc. 1999, 98-16, 247-256.
  • Aronson, B. J.; Kinser, A. K.; Passerini, S.; Smyrl, W. H.; Stein, A.; "Synthesis, Characterization, and Electrochemical Properties of Zinc and Magnesium Birnessites Prepared by a Low Temperature Route", Chem. Mater. 1999, 11, 949-957.

Mesoporous sieves based on polyoxometalates (including new inorganic anion-exchange materials)

Structures from polyoxometalate building blocks

  • Johnson, B.J.S.; Geers, S. A.; Brennessel, W. W.; Young, Jr., V. G.; Stein, A.; "A Coordination Network Containing Non-Coordinating Polyoxometalate Clusters as Counterions", Dalton Transactions 2003, 4678-4681.
  • Johnson, B. J. S.; Schroden, R. C.; Zhu, C.; Young Jr., V. G.; Stein, A.; "Design and Analysis of Chain and Network Structures from Organic Derivatives of Polyoxometalate Clusters", Inorg. Chem. 2002, 41, 2213-2218.
  • Johnson, B. J. S.; Zhu, C.; Schroden, R. C.; Stein, A.; "Synthesis and Characterization of 2D and 3D Structures from Organic Derivatives of Polyoxometalate Clusters-Role of Organic Moiety, Counterion, and Solvent", Inorg. Chem. 2001, 40, 5972-5978.
  • Johnson, B. J. S.; Buss, C. E.; Young, V. G.; Stein, A.; "Tetrabutylammonium Salt of Dodecamolybdotetrakis(p-cyanophenylarsonate)", Acta Cryst. 1999, C55, 549-551.

Sodalites and zeolites

  • Invited review: Stein, A.; "Advances in Microporous and Mesoporous Solids—Highlights of Recent Progress", Adv. Mater. 2003, 15, 763-775.
  • Invited review chapter: Stein, A.; Schroden, R. C.; “Designing Porous Solids Over Multiple Pore Size Regimes” in Nanostructured Catalysts, edited by S. L. Scott, C. M. Crudden, C. W. Jones, Kluwer-Plenum series on Nanostructure Science and Technology Vol. 3, 2002, 257-276, Kluwer-Plenum: Dordrecht, Netherlands.
  • Holland, B. T.; Abrams, L.; Stein, A.; "Dual Templating of Macroporous Silicates with Zeolitic Microporous Frameworks", J. Am. Chem. Soc. 1999, 121, 4308-4309.
  • Stein, A.; "NaBr-Sodalite"; in Robson, H. (ed.) Verified Syntheses of Zeolitic Materials, International Zeolite Association, Synthesis Commission, Microporous and Mesoporous Materials 1998, 22, 656-659.
  • Stein, A.; Ozin, G. A.; "Sodalite - An Old Material for Advanced Uses", in Mallouk, T. E. (ed.) Advances in the Synthesis and Reactivity of Solids 1994, 2, 93.
  • Stein, A.; Wehrle, B.: Jansen, M.; "Nitrogen Incorporation in AlPO4-5 Molecular Sieves by Thermal Ammonolysis", Zeolites 1993, 13, 291.
  • Jelinek, R.; Stein, A.; Ozin, G. A.; "81Br and 35Cl NMR Investigation of Sodium, Silver, Halo-Sodalite Semiconductor Supralattices", J. Am. Chem. Soc. 1993, 115, 2390.
  • Stein, A.; Ozin, G. A.; "Sodalite Supralattices: From Molecules to Clusters to Expanded Insulators, Semiconductors and Metals", in Ballmoos, R. V.; Higgins, J. B.; Tracy, M. M. (eds.), Proceedings of the 9th International Zeolite Conference, Montreal, 1992, Butterworth-Heinemann, Boston, 1993, 93.
  • Stein, A.; Ozin, G. A.; Stucky, G. D.; "Class B Sodalites: Nonstoichiometric Silver, Sodium Halosodalites", J. Am. Chem. Soc. 1992, 114, 8119.
  • Jelinek, R.; Chmelka, B. F.; Stein, A.; Ozin, G. A.; "Multinuclear Magic-Angle Spinning and Double Rotation NMR Study of the Synthesis and Assembly of a Sodalite Semiconductor Supralattice", J. Phys. Chem. 1992, 96, 6744 .
  • Jelinek, R.; Chmelka, B. F.; Stein, A.; Ozin, G. A.; "Multinuclear Solid-State NMR Study of a Sodalite Semiconductor Superlattice", Mater. Res. Soc. Symp. Proc. 1992, 272 (Chemical Processes in Inorganic Materials: Metal and Semiconductor Clusters and Colloids), 235.
  • Stein, A.; Ozin, G. A.; Macdonald, P. M.; Stucky, G. D.; Jelinek, R.; "Class A Sodalites: Silver, Sodium Halosodalites", J. Am. Chem. Soc. 1992, 114, 5171.
  • Ozin, G. A.; Kirkby, S.; Meszaros, M.; Ozkar, S.; Stein, A.; Stucky, G. D.; "Intrazeolite Semiconductor Quantum Dots and Quantum Superlattices - New Materials for Nonlinear Optical Applications", in Marder, S. R.; Sohn, J. E.; Stucky, G. D. (eds.) Materials for Nonlinear Optics, A. C. S. Symposium Series 455, American Chemical Society, Washington, 1991, 554.
  • Stein, A.; Meszaros, M.; Macdonald, P. M.; Ozin, G. A.; Stucky, G. D.; "Mixed Semiconductor Component Quantum Supralattices: Silver, Sodium Chloro,Iodo?Sodalites", Adv. Mater. 1991, 3, 306.
  • Stein, A.; Ozin, G. A.; "The Ferroin Test: a Sensitive and Convenient Probe of Internal Versus External Silver in Microporous Materials: Application to Silver Sodalites", J. Chem. Soc., Chem. Commun. 1991, 1455.
  • Stein, A.; Ozin, G. A.; Stucky, G. D.; "From the Molecule to an Expanded I?VII Semiconductor Quantum Superlattice: Silver,Sodium Halo?Sodalites", J. Am. Chem. Soc. 1990, 112, 904.
  • Stein, A.; Macdonald, P. M.; Ozin, G. A.; Stucky, G. D.; "Assembling a Semiconductor Quantum Superlattice One Atom at a Time: Nonstoichiometric Silver, Sodium Bromosodalites", J. Phys. Chem. 1990, 94, 6943.
  • Stein, A.; Ozin, G. A.; Stucky, G. D.; "Silver Sodalites ? A Chemistry Approach Towards Reversible Optical Data Storage", J. Soc. Photogr. Sci. Technol. Japan 1990, 53, 322.
  • Ozin, G. A.; Stein, A.; Stucky, G. D.; Godber, J. P.; "Silver Sodalites: Novel Optically Responsive Nanocomposites", in Atwood, J. (ed.) Inclusion Phenomena and Molecular Recognition, Plenum Press, New York, 1990, 379.
  • Ozin, G. A.; Stein, A.; Godber, J. P.; "Very High Density Optical Storage of Data in Silver Sodalites"; U. S. Patent 1990, 4,942,119.
  • Ozin, G. A.; Kuperman, A.; Stein, A.; "Advanced Zeolite Materials Science", Angew. Chem. Adv. Mater. 1989, 101, 373; Angew. Chem. Int. Ed. Engl. 1989, 28, 359.

Pseudomorphic transformations

  • Lytle, J. C.; Yan, H.; Turgeon, R. T.; Stein, A.; “Multistep, Low Temperature Pseudomorphic Transformations of Nanostructured Silica to Titania via a Titanium Oxyfluoride Intermediate”, Chem. Mater. 2004, 16, 3829-3837.

Polymer-clay nanocomposites

  • Chastek, T. T.; Stein, A.; Macosko, C.; “Hexadecyl-functionalized Lamellar Mesostructured Silicates and Aluminosilicates Designed for Polymer-Clay Nanocomposites. Part II: Dispersion in Organic Solvents and in Polystyrene Nanocomposites”, Polymer 2005, 46, 4431-4439.
  • Chastek, T. T.; Que, E. L.; Shore, J. S.; Lowy III, R. J.; Macosko, C.; Stein, A.; “Hexadecyl-functionalized Lamellar Mesostructured Silicates and Aluminosilicates Designed for Polymer-Clay Nanocomposites. Part I: Clay Synthesis and Structure”, Polymer 2005, 46, 4421-4430.

Reviews and other topics

  • Invited review: Stein, A.; "Advances in Microporous and Mesoporous Solids—Highlights of Recent Progress", Adv. Mater. 2003, 15, 763-775.
  • Invited review chapter: Schroden, R. C.; Stein, A.; "3D Ordered Macroporous Materials", Colloids and Colloid Assemblies: Synthesis, Modification, Organization and Utilization of Colloid Particles, F. Caruso (ed.), Wiley-VCH, Weinheim, Germany, 2004, 465-493.
  • Invited review chapter: Stein, A.; Schroden, R. C.; "Designing Porous Solids Over Multiple Pore Size Regimes" in Nanostructured Catalysts, edited by S. L. Scott, C. M. Crudden, C. W. Jones, Kluwer-Plenum series on Nanostructure Science and Technology, Vol. 3, 2002, 257-276, Kluwer-Plenum: Dordrecht, Netherlands.
  • Invited review: Stein, A.; Schroden, R. C.; "Colloidal Crystal Templating of Three-Dimensionally Ordered Macroporous Solids-Materials for Photonics and Beyond", Current Opinion in Solid State & Materials Science 2001, 5, 553-564.
  • Invited review: Stein, A.; "Sphere Templating Methods for Periodic Porous Solids", Microporous & Mesoporous Materials 2001, 44-45, 227-239.
  • Invited review: Blanford, C. F.; Yan, H., Schroden, R. C.; Al-Daous, M.; Stein, A.; "Gems of Chemistry and Physics: Three- Dimensionally Ordered Macroporous (3DOM) Metal Oxides", Adv. Mater. 2001, 13, 401-407.
  • Invited review chapter: Stein, A.; Melde, B.; "The Role of Surfactants and Amphiphiles in the Synthesis of Porous Inorganic Solids," in Reactions and Synthesis in Surfactant Systems, edited by J. Texter, Chapter 40, Marcel Dekker: New York, 2001, pp. 819-851.
  • Invited review: Stein, A.; Melde, B. J.; Schroden, R. C.; "Hybrid Inorganic-Organic Mesoporous Silicates - Nanoscopic Reactors Coming of Age", Adv. Mater. 2000, 12, 1403-1419.
  • Blanford, C.F.; Bentley, J.; Stein, A.; Carter, C.B., "An Investigation into Beam Damage of Mesoporous Materials", Microscopy and Microanalysis 1998, 4, suppl. 2, 712-713.
  • Blanford, C. F.; Aronson, B. J.; McKernan, S.; Stein, A.; Carter, C. B.; "The Study of Ti—MCM-41 by Tranmission Electron Microscopy", Microscopy and Microanalysis 1997, 3, suppl. 2, 1005-1006.
  • Stein, A.; "Nitrido-Sodalite Zn6[P12N24] as a Material for Reversible Hydrogen Encapsulation" (invited review), Chemtracts 1997, 10, 882-884.
  • Stein, A.; Keller, S.W.; Mallouk, T. E.; "Turning Down the Heat: Design and Mechanism in Solid State Synthesis", Science 1993, 259, 1558.
  • Stein, A.; Wehrle, B.: Jansen, M.; "Nitrogen Incorporation in AlPO4-5 Molecular Sieves by Thermal Ammonolysis", Zeolites 1993, 13, 291.
  • Glukhovtsev, M. N.; von R. Schleyer, P.; Stein, A.; "Can Four-Center Two-Electron Bonding Alone Provide Stability of a Molecule?", J. Phys. Chem. 1993, 97, 5541.
  • Stein, A.; Ozin, G. A.; "The Use of Fourier Transform Infrared Spectroscopy in the Characterization of Sodalite Framework Materials", FT-IR Spectral Lines 1991, 11, 6, Nicolet Instrument Corporation, Madison, Wisconsin, 53711.
  • Ozin, G. A.; Kuperman, A.; Stein, A.; "Advanced Zeolite Materials Science", Angew. Chem. Adv. Mater. 1989, 101, 373; Angew. Chem. Int. Ed. Engl. 1989, 28, 359.

Education

   

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Last updated and modified: August 11, 2005